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Publications 1994-1996
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View Diagram 9 Photo >>>> 1,
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9
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CHEMISTRY
EXPERIMENT AS "WORKS" OF STUDENTS USING FILTER
PAPER
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TORAY
SCIENCE FOUNDATION, JAPAN
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Aim
According to the
teaching guidance for science of the new high school curriculum to be
revised in 1994, teachers are strongly demanded to actively research
and develop teaching materials and by gathering audio and visual materials
and performing interesting experiments to aid students to deepen their
interest and understanding in science.
However, I, as a
science teacher, am disappointed with the present situation of the students'
low interest in science which is caused by too much audio and visual
information and becoming too familiar to them that they have lost their
desire to try what they have seen and heard by themselves.
On the other hand,
the teachers have lapsed into the tendency to teach science for the
sake of passing entrance examinations and therefore to emphasize theory
and calculations, so that classes are done with paper and pencil and
with few experiments to back up the theories. In this way, the teachers
are responsible for the lack in expansion in science classes.
This research was
inspired by a girl student whom I saw take home a filter paper used
in an experiment as if it was something valuable. This gave me the idea
of a "take home experiment work" as you would take home pieces
of work of art or home economics.
Instead of pouring
experiment results down the drain when the experiment is over, my idea
is to keep the students' results on filter paper, so that each student
can preserve their experiment results and in so doing sustain their
enthusiasm in learning science.
Outline
1. Dissolve more
than two chemicals in water and spot a small amount onto filter paper
using a capillary and cause various chemical reactions to occur in the
centre of the filter paper. (Photos 9-1P to 3P).
In this way, each student is able to take their time in observing the
capillarity change before and after a reaction, which would not be possible
with a test tube.
2. In the case of inorganic chemical reactions, various reactions of
solubility, ionic reaction, precipitation, neutralization, oxidation-reduction
reaction of compounds, group reaction of metallic ions and metal complex
can be confirmed by experimenting on filter paper.
3. As for organic chemical reactions, colour reaction for confirming
functional group is suited for this method, as well as confirmation
of carboxyl group and carbonyl group, or separation of various amino
acids, synthesis of dyestuff, separation and confirmation of natural
compounds and the like.
4. We cannot only do qualitative analysis of chemical change by colour
reaction but also by confirming the shades of colours of various concentration
of solutions, we may conduct a semi-quantitative analysis. We can make
a concentration chart by colour reactions of such inorganic ions as
copper, iron, chrome and manganese ions, and in so doing can confirm
the concentration of waste fluids without using the costly litmus paper.
5. This method is not only effective for confirming chemical change
by colour reaction but also for confirming compounds by smell. Particularly,
for confirming the relationship with smell of functional group of organic
compounds, isomer and molecular weight, I named such method of analysing
substances by smell "hanalysis" (hana=nose + analysis), which
delighted the students very much. (Photo 9-4P).
6. Experiment of burning organic compounds absorbed in a swab and estimating
the content amount of carbon from the state during combustion also interested
the students very much. (Photos 9-5P to 7P).
7. By this method, students can confirm by just smelling the tip of
the swab the appearance of soot, the smell before burning and after
in the oxidized state, the smell of the oxidized compound, etc.
Method of Making
Teaching Material
1. Filter paper
for use in Experiment
The filter paper
used here is the round filter paper commonly used in students' experiments.
On it, the students will each draw lines with crayons or oil-based
ink as shown in photos 9-8P & 9P using a scale in sizes suitable
for each experiment. This is in order to prevent chemical reactions
from occurring among the different solutions tested on the paper.
Therefore, for aqueous chemicals we will use oil-based ink or crayon
but for oil-based chemicals, especially for nonpolar organic compounds,
we must draw the lines with water-based ink or else they may be printed.
If square filter paper used for paper chromatography (40 x 40cm) can
be obtained, it would be possible to raise the efficiency of experiments
by printing the contents as in photos 9-12P to 16P which will unify
the style. Instructions may also be printed.
If instructions of experiment conditions and comments are printed,
this should greatly help the students especially for complicated reactions.
Also, if filter paper for chromatography (2 x 40cm) available at stores
can be used, many spots may be taken so that a standard colour chart
is made for comparing colours of several concentrations of solutions
for semi-quantitative analysis, or by spotting with swab various acid
salt radicals onto various pH indicators prespotted onto each area.
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Photo
9-12P |
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Reaction between Fe2+ and Fe3+ |
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Photo
9-13P |
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Reaction between metallic ions and various reagents. |
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Photo
9-14P |
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Colour scale of different Cu concentration and NH, HS. |
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Photo
9-15P |
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Property of water-based/oil-based ink with alcohol |
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Photo
9-16P |
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Property of water-based/oil-based ink with fragrant |
2. Swab for use
in Experiment
Initially, I
tried to spot solutions onto filter paper using a glass capillary
and hoped that by capillarity solutions A and B would react in the
centre of the filter paper.
However, the size of the spots differed from capillary to capillary
and depending on the students using them. There was also fear of capillaries
breaking during the experiment which might injure the students' hands.
I therefore thought to substitute swab for capillary.
With swabs, the sizes of the spots became uniform, there was less
failure, and with swabs in both ends, one may absorb solutions A and
B on each end of one swab which is very convenient. We are also able
to get fashionable swabs of which the plastic axis come in various
different colours. This is useful for sorting out the various types
of compounds.
Recently, there are also types of swab that have earpick on one end.
This is very convenient for experiments in which it is necessary to
spoon a uniform amount of powder.
Guidance Method
This method of chemistry
experiments using filter paper instead of test tubes enables students
to confirm by observation the state before and after a reaction of inorganic
chemical reactions as well as organic chemical reactions by intentionally
selecting chemicals that change colour when undergoing chemical reaction.
Moreover, by making
use of the different shades produced in colour reactions of chemical
change, it is possible to teach chemistry in a semi-quantitative way
as well as in the qualitative sense.
For those reactions
that need heating or cooling, if it is up to 200oC the reaction may
be done by placing the filter paper on a heating plate or iron.
To cool, we may
place a sheet glass or aluminum foil over an instant refrigerant or
ice, and set filter paper on top for reaction.
If we want to regulate
the temperature, as filter paper will reach the desired temperature
instantly, wrapping a filter paper around a beaker filled with water
of the right temperature will do the trick.
In reaction with
gas, we may first absorb the solution onto the filter paper and then
hold the gas up to the paper to let them react.
As reaction occurs
much faster with filter paper than with test tubes, it is convenient
to use this fact to teach students that in the natural world the oxidized
state is the most stable form. However, if oxidization is to be prevented,
we may seal the reacted spot with cellophane tape and preserve the state
permanently.
Effectiveness upon
actual practice
1. Students had
tendency to avoid chemistry experiments because of the 3Ks, i.e. "kowai"
(frightening), "kusai" (bad smell) and "kitanai"
(dirty) but this method of experimenting has helped get rid of that
attitude. The students began to challenge "bad smells" and
eagerly took home experiment results to show their parents.
2. Chemistry experiments are conducted by "observing, listening
and recording". One should observe well, listen attentively to
the teacher's explanation and instructions, and record what one has
seen and heard. The students were motivated to do all these things.
3. The gap in the interest towards chemistry experiment between girls
and boys shrank. Where there was a subconscious fear towards the danger
and harmful effects of chemicals, this method of reacting chemicals
on filter paper use an extremely small amount so that, feeling safer,
each student can without aid conduct their own experiment. All the students
will be able to clear up the experiment together too so the feeling
of unfairness is gone.
4. As the reaction is done on filter paper, the experiment is over at
once, so it is possible to increase the items of experiment. In the
past, much time and expense was necessary to dispose of the waste fluid
in test tubes but this has become unnecessary. A great amount of chemicals
is also saved.
5. The experiment became the "works" of each student and could
be taken back to their classrooms. Therefore, the experiment could be
re-enacted in class which helped expand the contents of the class.
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View Diagram 9 Photo >>>> 1,
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