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Publications 1994-1996
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9
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CHEMISTRY
EXPERIMENT AS "WORKS" OF
STUDENTS USING FILTER PAPER
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TORAY
SCIENCE FOUNDATION, JAPAN
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Aim
According
to the teaching guidance for science of the new high
school curriculum to be revised in 1994, teachers
are strongly demanded to actively research and develop
teaching materials and by gathering audio and visual
materials and performing interesting experiments to
aid students to deepen their interest and understanding
in science.
However,
I, as a science teacher, am disappointed with the
present situation of the students' low interest in
science which is caused by too much audio and visual
information and becoming too familiar to them that
they have lost their desire to try what they have
seen and heard by themselves.
On
the other hand, the teachers have lapsed into the
tendency to teach science for the sake of passing
entrance examinations and therefore to emphasize theory
and calculations, so that classes are done with paper
and pencil and with few experiments to back up the
theories. In this way, the teachers are responsible
for the lack in expansion in science classes.
This
research was inspired by a girl student whom I saw
take home a filter paper used in an experiment as
if it was something valuable. This gave me the idea
of a "take home experiment work" as you
would take home pieces of work of art or home economics.
Instead
of pouring experiment results down the drain when
the experiment is over, my idea is to keep the students'
results on filter paper, so that each student can
preserve their experiment results and in so doing
sustain their enthusiasm in learning science.
Outline
1.
Dissolve more than two chemicals in water and spot
a small amount onto filter paper using a capillary
and cause various chemical reactions to occur in the
centre of the filter paper. (Photos 9-1P to 3P).
In this way, each student is able to take their time
in observing the capillarity change before and after
a reaction, which would not be possible with a test
tube.
2. In the case of inorganic chemical reactions, various
reactions of solubility, ionic reaction, precipitation,
neutralization, oxidation-reduction reaction of compounds,
group reaction of metallic ions and metal complex
can be confirmed by experimenting on filter paper.
3. As for organic chemical reactions, colour reaction
for confirming functional group is suited for this
method, as well as confirmation of carboxyl group
and carbonyl group, or separation of various amino
acids, synthesis of dyestuff, separation and confirmation
of natural compounds and the like.
4. We cannot only do qualitative analysis of chemical
change by colour reaction but also by confirming the
shades of colours of various concentration of solutions,
we may conduct a semi-quantitative analysis. We can
make a concentration chart by colour reactions of
such inorganic ions as copper, iron, chrome and manganese
ions, and in so doing can confirm the concentration
of waste fluids without using the costly litmus paper.
5. This method is not only effective for confirming
chemical change by colour reaction but also for confirming
compounds by smell. Particularly, for confirming the
relationship with smell of functional group of organic
compounds, isomer and molecular weight, I named such
method of analysing substances by smell "hanalysis"
(hana=nose + analysis), which delighted the students
very much. (Photo 9-4P).
6. Experiment of burning organic compounds absorbed
in a swab and estimating the content amount of carbon
from the state during combustion also interested the
students very much. (Photos 9-5P to 7P).
7. By this method, students can confirm by just smelling
the tip of the swab the appearance of soot, the smell
before burning and after in the oxidized state, the
smell of the oxidized compound, etc.
Method
of Making Teaching Material
1.
Filter paper for use in Experiment
The
filter paper used here is the round filter paper
commonly used in students' experiments. On it, the
students will each draw lines with crayons or oil-based
ink as shown in photos 9-8P & 9P using a scale
in sizes suitable for each experiment. This is in
order to prevent chemical reactions from occurring
among the different solutions tested on the paper.
Therefore, for aqueous chemicals we will use oil-based
ink or crayon but for oil-based chemicals, especially
for nonpolar organic compounds, we must draw the
lines with water-based ink or else they may be printed.
If square filter paper used for paper chromatography
(40 x 40cm) can be obtained, it would be possible
to raise the efficiency of experiments by printing
the contents as in photos 9-12P to 16P which will
unify the style. Instructions may also be printed.
If instructions of experiment conditions and comments
are printed, this should greatly help the students
especially for complicated reactions.
Also, if filter paper for chromatography (2 x 40cm)
available at stores can be used, many spots may
be taken so that a standard colour chart is made
for comparing colours of several concentrations
of solutions for semi-quantitative analysis, or
by spotting with swab various acid salt radicals
onto various pH indicators prespotted onto each
area.
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Photo
9-12P |
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Reaction between Fe2+ and Fe3+ |
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Photo
9-13P |
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Reaction between metallic ions and various reagents. |
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Photo
9-14P |
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Colour scale of different Cu concentration and NH,
HS. |
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Photo
9-15P |
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Property of water-based/oil-based ink with alcohol |
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Photo
9-16P |
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Property of water-based/oil-based ink with fragrant
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2.
Swab for use in Experiment
Initially, I tried to spot solutions onto filter
paper using a glass capillary and hoped that by
capillarity solutions A and B would react in the
centre of the filter paper.
However, the size of the spots differed from capillary
to capillary and depending on the students using
them. There was also fear of capillaries breaking
during the experiment which might injure the students'
hands. I therefore thought to substitute swab for
capillary.
With swabs, the sizes of the spots became uniform,
there was less failure, and with swabs in both ends,
one may absorb solutions A and B on each end of
one swab which is very convenient. We are also able
to get fashionable swabs of which the plastic axis
come in various different colours. This is useful
for sorting out the various types of compounds.
Recently, there are also types of swab that have
earpick on one end. This is very convenient for
experiments in which it is necessary to spoon a
uniform amount of powder.
Guidance
Method
This
method of chemistry experiments using filter paper
instead of test tubes enables students to confirm
by observation the state before and after a reaction
of inorganic chemical reactions as well as organic
chemical reactions by intentionally selecting chemicals
that change colour when undergoing chemical reaction.
Moreover,
by making use of the different shades produced in
colour reactions of chemical change, it is possible
to teach chemistry in a semi-quantitative way as well
as in the qualitative sense.
For
those reactions that need heating or cooling, if it
is up to 200oC the reaction may be done by placing
the filter paper on a heating plate or iron.
To
cool, we may place a sheet glass or aluminum foil
over an instant refrigerant or ice, and set filter
paper on top for reaction.
If
we want to regulate the temperature, as filter paper
will reach the desired temperature instantly, wrapping
a filter paper around a beaker filled with water of
the right temperature will do the trick.
In
reaction with gas, we may first absorb the solution
onto the filter paper and then hold the gas up to
the paper to let them react.
As
reaction occurs much faster with filter paper than
with test tubes, it is convenient to use this fact
to teach students that in the natural world the oxidized
state is the most stable form. However, if oxidization
is to be prevented, we may seal the reacted spot with
cellophane tape and preserve the state permanently.
Effectiveness
upon actual practice
1.
Students had tendency to avoid chemistry experiments
because of the 3Ks, i.e. "kowai" (frightening),
"kusai" (bad smell) and "kitanai"
(dirty) but this method of experimenting has helped
get rid of that attitude. The students began to challenge
"bad smells" and eagerly took home experiment
results to show their parents.
2. Chemistry experiments are conducted by "observing,
listening and recording". One should observe
well, listen attentively to the teacher's explanation
and instructions, and record what one has seen and
heard. The students were motivated to do all these
things.
3. The gap in the interest towards chemistry experiment
between girls and boys shrank. Where there was a subconscious
fear towards the danger and harmful effects of chemicals,
this method of reacting chemicals on filter paper
use an extremely small amount so that, feeling safer,
each student can without aid conduct their own experiment.
All the students will be able to clear up the experiment
together too so the feeling of unfairness is gone.
4. As the reaction is done on filter paper, the experiment
is over at once, so it is possible to increase the
items of experiment. In the past, much time and expense
was necessary to dispose of the waste fluid in test
tubes but this has become unnecessary. A great amount
of chemicals is also saved.
5. The experiment became the "works" of
each student and could be taken back to their classrooms.
Therefore, the experiment could be re-enacted in class
which helped expand the contents of the class.
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View Diagram 9 Photo >>>>
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